Probing equilibrium glass flow up to exapoise viscosities

TítolProbing equilibrium glass flow up to exapoise viscosities
Tipus de publicacióJournal Article
Any de publicació2015
AutorsPogna, EAA, Rodríguez-Tinoco, C, Cerullo, G, Ferrante, C, Rodríguez-Viejo, J, Scopigno, T
JournalProceedings of the National Academy of Sciences

Glasses are out-of-equilibrium systems aging under the crystallization threat. During ordinary glass formation, the atomic diffusion slows down, rendering its experimental investigation impractically long, to the extent that a timescale divergence is taken for granted by many. We circumvent these limitations here, taking advantage of a wide family of glasses rapidly obtained by physical vapor deposition directly into the solid state, endowed with different “ages” rivaling those reached by standard cooling and waiting for millennia. Isothermally probing the mechanical response of each of these glasses, we infer a correspondence with viscosity along the equilibrium line, up to exapoise values. We find a dependence of the elastic modulus on the glass age, which, traced back to the temperature steepness index of the viscosity, tears down one of the cornerstones of several glass transition theories: the dynamical divergence. Critically, our results suggest that the conventional wisdom picture of a glass ceasing to flow at finite temperature could be wrong.

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